Mytsuk O. Chemiluminescent reactions of methosulfate 9.10-dimethylacridinium with potassium peroxomonosulfate and diperoxyadipinic acid and determination of Cu(II), Ni(II), V(IV), Cr(VI) on the base of these reactions

Thesis is devoted to extending of chemiluminescence ana-lysis through investigation of the chemiluminescence reactions of methosulfate 9,10-dimethylacridinium with new oxidazion reagents. The results of investigation of peroxomonosulfate properties, regularities of chemiluminescence reactions of methosulfate 9,10-dimethylacridinium with peroxomonosulfate in a wide range of medium acidity and with peroxyadipinic acid in acidic medium have been presented in the thesis. The schemes of formation of the chemiluminescence emiter for these reactiona have been proposed. Peculiarities of intensifying influence of metal on the chemiluminescence parameters have been studied and high sensitive and expressive methods of determination of Cu(II), Ni(II), V(IV), Cr(VI), peroxomonosulfate and peroxodisulfate have been proposed.