Mel'nyk G. Thermodynamic Properties of Silicon Containing Acetylene Peroxides

The Dissertation is devoted to the investigation of thermodynamic properties of silicon containing acetylene peroxides. Combustion enthalpies, formation enthalpies for condensed and gas state, temperature dependencies of saturated vapour pressure and evaporation enthalpies have been determined. Some fragments of additive Benson scheme have been calculated. On the base of liquid - vapour isothermic equilibrium data for binary systems with silicon containing acetylene peroxide activity coefficients of components and excess thermodynamic properties (enthalpies, entropies and Gibbs energies) have been determined. Key words: silicon containing acetylene peroxides, combustion enthalpy, formation enthalpy, evaporation enthalpy, saturated vapour pressure, activity coefficients, excess enthalpy, excess Gibbs energy.