Konoshchuk N. Physico-chemical and electrochemical properties of conducting polymer materials based on 3-substituted thiophenes

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0402U003974

Applicant for

Specialization

  • 02.00.04 - Фізична хімія

17-12-2002

Specialized Academic Board

Д 26.190.01

L. V. Pisarzhevskii Institute Of Physical Chemistry of The National Academy of Sciences of Ukraine

Essay

For the first time the poly-3-phenylthiophene films capable to reversible electrochemical n-doping with lithiuml cations are synthesized. The p- and n-doping mechanism for 3-substituted polythiophenes are proposed. It's found the possibility of the charge transfer from poly-3-methyl-(P3MT) and poly-3-phenylthiophene (P3PT) polymer matrix on the heteropolyanion-dopants Keggine type. А number of 3-phenylthiophene and pyrrole copolymer films and сomposites based on P3MT and P3PT with different carbon materials are obtained.

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