Greshyschkina G. Physico-chemical properties and structure of water solutions of chloride, nitrate and sulfate of 3d-transition metals

The thesis is devoted to study of structure and physicochemical properties of water solutions of electrolytes. Sets, that all processes flow past about an ion, happen for account of specific short-range interactions of an ion to molecules lead, in a corollary that the mobility last varies. As structural-dynamic characteristics of these processes are designed and are surveyed of structural composite partial boundary molar volume of individual ions. And coefficient of viscosity of the equation Jones-Dole, which were designed for the first time for the given temperature band. Obtained from experimental dates of an conductivity of asymmetrical electrolytes the concentration dependence of parameter a in the equation of Robins-Stokes, has enabled to separate all a concentration interval into field, which correspond to boundaries by complete that of a long-range hydration. For symmetric electrolytes the model "of noninteracting orbs" is offered which allows, as a first approximation to receive concentration dependence of parameter a.