Doroshchuk V. The particularities of micellar-extraction preconcentration of trace components by phases of nonionic surfactants at cloud point temperature

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0403U003419

Applicant for

Specialization

  • 02.00.02 - Аналітична хімія

27-10-2003

Specialized Academic Board

Д 26.001.03

Taras Shevchenko National University of Kyiv

Essay

The thesis is devoted to the development of theoretical and practical approaches of the application of micellar extraction by the phases of nonionic surfactants at cloud-point temperature for the trace components preconcentration. The influence of the hydrophobity, charge and structure of substrate molecules onto their distribution in the water - nonionic surfactant phase system has been investigated on the example of carbonic acids, organic analytical reagents and their metal complexes. The recommendations for the obtaining of effective micellar-extraction system has been developed. On the basis of investigations it was proposed the procedures for spectroscopic determination of some metals in the tap and natural waters with micellar-extraction preconcentration.

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