Gorbatenko N. Action of supramolecular halide complexes on acylperoxide decomposition and initiation of radical-chain oxidation by them.

The objects are mechanism and kinetic scheme of the reaction between benzoyl peroxide and supramolecular complex KBr-18-crown-6 in acetonitrile, kinetic scheme of the initiation reaction at the cumene oxidation. The aims to investigate reaction of acylperoxide with supramolecular complexes that consist haloid. Methods of research are IR-, UV-spectroscopes, iodometric, argentometric, acid-base titration, the gas-liquid chromatography, preparative chromatography, flash chromatography, liqiudephase oxidation. The action of supramolecular compounds on the kinetic and products composition is investigated. Liqiudephase cumene oxidation that is initiated by the peroxide - supramolecular complex systems is studied. Theoretic analysis of interaction of peroxide with supramolecular haloidcomlexe is carried out. Sphere of use is initiation of the low temperature radical-chain processes.