Gerasova V. Redox catalysis by systems based on [CuL][MnCl4] and [CuL][ZnCl4]

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0409U005416

Applicant for

Specialization

  • 02.00.04 - Фізична хімія

30-11-2009

Specialized Academic Board

Д 26.001.03

Taras Shevchenko National University of Kyiv

Essay

The dissertation is devoted to investigation of catalytic properties of systems based on [CuL][MCl4], M - Zn, Mn, L - 4,6,6-trimethyl-1,9-diamino-3,7-diazanona-3-еne and 1,15-dihydroxy-7,9,9-trimethyl- 3,6,10,13-tetraаzаpentadeca-6-еn in H2O2 decomposition and ascorbic acid oxidation by O2 in liquid phase. It was shown that using of [CuL][MCl4] increase rate of soot oxidation in 4-11 times. It was found that a greater catalytic activity in hydrogen oxidation have the heat treatment samples prepared by adsorption than by impregnation.

Files

Similar theses