Kartashova T. The oxidation of carbon monoxide and carbon on multicomponent catalysts based on copper, cobalt and iron

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0411U001499

Applicant for

Specialization

  • 02.00.04 - Фізична хімія

28-02-2011

Specialized Academic Board

Д26.001.03

Essay

The dissertation is devoted to synthesis, investigation of the structure and study of adsorption and catalytic properties of oxide Cu-Co-Fe system supported on various carbon supports (TEG, SAC) in the CO oxidation. The effect of influence of modifying medium on the formation of the active sites and, consequently, on the catalytic activity of the samples is studied. It is shown that treating the carbon support with H2O2 and HNO3 leads to the formation of oxygen-containing groups in the surface layer. Addition of active mass or nitric acid treatment leds to the increase of surface functional groups concentration and lowers the temperature of the beginning of their decomposition and desorption.

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