Savchuk A. Electrochemical behaviour of platinum metals (Rh, Ir,Ru) in low-temperature molten electrolytes

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0411U004885

Thesis Registration Form

0411U004885.pdf

Applicant for

Specialization

  • 02.00.05 - Електрохімія

14-10-2011

Specialized Academic Board

Д 26.218.01

V.I. Vernadskii Institute of General & Inorganic Chemistry NAS of Ukraine

Essay

The thesis deals with the study of mechanism and kinetics of electrode processes of platinum metals in low temperature metals based on carbamide, acetamide, imidazole, thiocarbamide and their mixtures with NH4Cl and with the development of new methods for the electrodeposition of sound Rh, Ir, Ru coatings on metallic substrates. Sound 6.2, 4.6 and 12 mkm thick coatings have been obtained for Rh, Ir and Ru respectively by the electrolysis of carbamide-containing melt and 6.8, 4.6 and 9-12 mkm thick coating from an acetamide-chloride melt. All electrodeposits are fine-crystalline; the size of crystals is 50-500 nm.

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Files

Автореферат_СавчукА.В.doc

Диссертация_Савчук А.В..doc

Диссертация_Савчук А.В..doc

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