Goncharenko S. Activation of aluminium and magnesium with IIb, IVa and Va subgroup metals for hydrogen extraction from water.

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0411U004899

Thesis Registration Form

0411U004899.pdf

Applicant for

Goncharenko Sergey Gennad'evich

Specialization

02.00.04 - Фізична хімія

Date of defense

14-10-2011

Specialized Academic Board

Д 26.218.01

V.I. Vernadskii Institute of General & Inorganic Chemistry NAS of Ukraine

Essay

The interaction between alloys based on IIb, Iva and Va Mendeleyev's groups metals activated Al and Mg and water with hydrogen evolution in the temperature range 150-325 C has been studied in this dissertation work. The base kinetic parameters of process of interaction between alloys and water with hydrogen evolution by volumometric methods have been determined and has been shown that these alloys evolves hydrogen from water with high rate; it reaches 24100 LH2/(m2·min) at 325 C. The phase composition of alloys has been determined by X-ray phase analysis. An analysis of the products of interaction between alloys and water with hydrogen evolution showed that the reaction products are Mg(OH)2 and AlOOH. On a base of electron microscopy data the nano- and microstructure of alloys have been shown.

Thesis supervisor

Kozin Leonid Fomich

Official opponents

Колбасов Геннадій Якович
Тітов Володимир Євгенович

Files

Автореферат--01.doc

Диссертация--01ВСТУП--01титульна сторінка.doc

Диссертация--01ВСТУП--02ЗМІСТ.doc

Диссертация--01ВСТУП--03Перелык скорочень.doc

Диссертация--01ВСТУП--04ВСТУП.doc

Диссертация--02Литогляд--1.doc

Диссертация--03Експериментальна частина--2--2.doc

Диссертация--03Експериментальна частина--3--3.doc

Диссертация--03Експериментальна частина--4--4.doc

Диссертация--03Експериментальна частина--5--5.doc

Диссертация--03Експериментальна частина--6--6.doc

Диссертация--03Експериментальна частина--7--7.doc

Диссертация--04Висновки--Висновки.doc

Диссертация--05Додатки--2--Диаграмы состояния.doc

Диссертация--06Лiтература--Литература.doc

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