Kyseliova Y. Heterogeneous association with anions phenolsulfonephthalein and its derivatives in aqueous solutions

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0411U006799

Applicant for

Specialization

  • 02.00.04 - Фізична хімія

20-10-2011

Specialized Academic Board

Д 64.051.14

V.N. Karazin Kharkiv National University

Essay

Object of investigation - The association phenomenon between cations and аniones dyes in water solutions which contain additives of ionic PAV or organic solvent (acetone). The Research objective - to establish the factors influencing interaction one- or two-charging sulfonephthaleins anions of dyes with cations of cyanines by dyes. Methods of investigation and apparatus - spectrophotometry (spectrophotometr). Theoretical and practical results - the new way of definition of the maintenance of acetone in water is developed. The data about stability and spectral characteristics diverse association can be taken as a principle purposeful search of new systems association dyes. Novelty - spectral, equilibrium and thermodynamic characteristics diverse association one- both two-charging phenolsulfonephtaleins aneones and chains its bromine and alkil derivatives are defined, compared ecsperemently (association constants) and theoretically received (enthalpy formations) characteristics. Introduction degree - it is included in educational process. Field of application - physical chemistry of organic systems.

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