But Y. Several electronic processes of charge transfer and electrochemically active complexes in ionic molybdate containing melts

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0412U000205

Applicant for

Specialization

  • 02.00.04 - Фізична хімія

26-01-2012

Specialized Academic Board

Д 26.218.01

V.I. Vernadskii Institute of General & Inorganic Chemistry NAS of Ukraine

Essay

By means of ab initio calculations the phenomenon of formation and the mode of multi-electronic transfers of EAС resumption in molybdate containing melts has been explored and substantiated under effect of the acid-base properties of the medium, electric field and electrode surface. It has been proved that the acidic properties of a melt predominate in the procedure of EAС formation and resumption, the latter increases under effect of adsorption properties of electrode surface depending on the intensity of electric field.

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