Serdyuk G. Catalysis of oxidation of carbonyl compounds with amines by molecular oxygen

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0412U001447

Thesis Registration Form

0412U001447.pdf

Applicant for

Specialization

  • 02.00.04 - Фізична хімія

23-02-2012

Specialized Academic Board

Д 11.216.01.

Essay

The range of catalytic activity of amines with different structure in the liquid-phase oxidation of anthrone in polar media, the mechanism of the process and kinetic equation had been suggested. Nature of the solvent significantly influences the process. It was found that key stage in first process is formation of complexes of different composition. For the possible intermediate species - azomethines formed from the carbonyl component - substituted benzaldehydes and amines - 3-аmino-4-aryltiophene or 5-аmino-4-arylpyrazoles identified the influence of structural factors on the rate of their oxidative cyclization.

Read more

Files

aref.doc

dis.doc

Similar theses

0424U000028

Olha A. Kovalenko

PECULIARITIES OF THE FORMATION OF ISO- AND ANISOTROPIC BARIUM TITANATE NANOSTRUCTURES

0523U100032

Kytsia Andrii R.

Kinetics of the formation of Ag-, Cu- and Ni-containing nanoparticles in solutions

0523U100018

Boichyshyn Lidia M.

Nanostructuring and its influence on the physical and chemical properties of amorphous alloys based on aluminum and iron

0522U100077

Shmychkova Olesia Borysivna

Electrochemical formation of PbO2-based composites and their electrocatalytic properties

0421U104064

Kondratiuk Andrii S

Mechanochemical preparation, structure, spectral and functional characteristics of modified graphenes, graphene-like carbon nitride and tungsten disulfide