Potapenko A. Electrochemical properties of systems oxygen electrode materials (LiMn2O4, LiV3O8, TiO2) - salt-solvate electrolyte

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0412U005722

Applicant for

Specialization

  • 02.00.05 - Електрохімія

20-09-2012

Specialized Academic Board

Д 26.218.01

V.I. Vernadskii Institute of General & Inorganic Chemistry NAS of Ukraine

Essay

Properties of salt-solvate systems Lithium salt - glyme solvent have been investigated as electrolytes for chemical power sources. Phisico-chemical properties of obtained electrolyte system such as temperature of melting (or glass transition temperature), thermally stability, viscosity, conductivity and interval of electrochemical stability have been determined. Electrochemical behavior of different structure of oxide electrode materials in media of salt-solvate electrolytes has been investigated. Correlation between kinetic and diffusion parameters has been determined when lithium intercalate into structure of electrode materials. Possibility of using salt-solvates as a electrolytes for lithium ion batteries on a base of LiV3O8 / LiMn2O4 has been shown.

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