Babkin R. Physical properties of 3d-ions in complexes with a different symmetry: an effective nuclear charge approximation

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0415U004808

Thesis Registration Form

0415U004808.pdf

Applicant for

Specialization

  • 01.04.07 - Фізика твердого тіла

29-09-2015

Specialized Academic Board

Д 64.175.03

B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine

Essay

This thesis focuses on changes in spin and orbital subsystems of 3d-metal ions in complexes with different symmetry by changing the parameter "effective nuclear charge" and the definition of this parameter from experimental data. The schemes of determination of the effective nuclear charge of 3d-ions, located in the crystal matrix of arbitrary symmetry. The proposed schemes of spin state diagrams and adiabatic surfaces allowed to examine the evolution of the spin and orbital states of ions under the influence of arbitrary 3d-ion environment distortions and changing of the effective nuclear charge value.

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Files

aref.doc

aref.doc

dis.doc

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