Chernikova E. Models activation of the covalent bond by nanostructural catalysts in the oxidizing reaction

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0416U001276

Thesis Registration Form

0416U001276.pdf

Applicant for

Chernikova Elena Mikolaivna

Specialization

01.04.07 - Фізика твердого тіла

Date of defense

20-01-2016

Specialized Academic Board

Д 26.199.01

V. Lashkaryov Institute of semiconductor physics

Essay

It has been discovered that the location of ethylene glycol molecule center near the catalyst edge destroys the bond between atoms C-C more effectively. It has been demonstrated that acceleration of the Si oxidation process in the Cr monolayer presence is carried due to the attenuation of Si-Si bonds and reactivity of Cr monolayer on silicon film increases when Cr atoms are partially oxidized. The work illustrates that the mechanical stress and the presence of dissociated oxygen have the greatest impact on increasing electron bimetallic catalyst activity during the oxidation of methanol with using bimetallic layered mechanically strained Pt,Ni-based catalysts. It is determined a significant difference in the energies of the nanoparticles of hematite and quartz.

Thesis supervisor

Balabai Ruslana Mihaylovna

Official opponents

Глушко Є.Я.
Дмитренко О.П.

Files

aref.doc

dis.doc

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