Shkarban R. Laws of phase and structure formation of nanoscaled Co-Sb films on the thermally oxidized single-crystal silicon substrates

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0416U004064

Applicant for

Specialization

  • 05.16.01 - Металознавство та термічна обробка металів

27-09-2016

Specialized Academic Board

Д 26.002.12

Publishing and Printing Institute of Igor Sikorsky Kyiv Polytechnic Institute

Essay

The dissertation is devoted to the establishment of the laws of thermally stimulated formation of phase and structure composition of skutterudite CoSb3 based films, as well as the influence of the nanoscaling factor on their thermoelectric properties. Metallographic studies allowed to reveal the interval of thermal stability of phase composition and structure with enhanced homogeneity region of CoSb3 phase and minimal surface roughness, increased structure defectivity due to the antimony sublimation and grain size reduction, that, taking into account the nanoscale factor, leads to an increase in the coefficient of the thermoelectric efficiency of Co-Sb.

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