Kos R. Thermodynamic properties of ethyl esters of 3-(5-aryl-2-furyl)-2-cyanoacrylic acids and their solutions

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0417U004059

Applicant for

Specialization

  • 02.00.04 - Фізична хімія

04-10-2017

Specialized Academic Board

Д 35.051.10

Ivan Franko National University of Lviv

Essay

The thermodynamic properties of seven esters of furanacrylic acid were studied: the enthalpies of combustion; enthalpies of formation in the condensed state; enthalpies of sublimation; enthalpies of dissolution; temperature dependences of vapor pressure and solubility in organic solvents. The possibility of using of existing additive schemes for calculating the thermodynamic characteristics of ethyl esters of furanacrylic acids were analyzed; Addition of the additive Benson scheme by group contributions typical for this class of compounds is carried out. The effect of the structure of the studied esters on the parameters of their dissolution is established.

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