Porokhonko V. Electroslag remelting of titanium alloys under influence of external longitudinal magnetic fields.

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0421U101398

Applicant for

Specialization

  • 05.16.02 - Металургія чорних і кольорових металів та спеціальних сплавів

26-04-2021

Specialized Academic Board

Д 26.182.02

E.O.Paton Elektric Welding Institute National Academy of scinces of Ukraine

Essay

Dissertation is devoted to determination of regularities of processes of metal melting, transferring and crystallization at ESR in conditions of effect of external constant and impulse longitudinal magnetic fields and development of technical recommendations on their application for melting of titanium alloys. The peculiarities of melting of the consumable electrode, the nature of formation and detachment of electrode metal droplets and their movement in the slag pool at ESR under the conditions of external magnetic fields are investigated by mean of physical modeling. The experiments were carried out according to different schemes using alternating, direct and modulated melting current under the action of an external constant or pulsed longitudinal magnetic field. As a result of these experiments it was found that under the influence of a longitudinal magnetic field torroidal hydrodynamic flows in the slag pool are transformed into horizontal rotation around its axis, which leads to deformation of the free surface of the slag pool and the interface slag-metal pools. The amount of deformation of the pool free surface depends on the speed of its rotation. By means of the physical modeling a number of laws was established. In particular, use of longitudinal magnetic field induction of 0.2...0.35 Tesla leads to a decrease in the frequency of detachment of electrode metal (by 20...30%), a decrease in their average weight (up to 10...50%), an increase in their trajectories of movement (up to 30...160%) and the period of passing through slag pool (from 0,2...0,25 to 0,4... 0,8 s), as well as to the dispersal of places where they fall on the mirror of the liquid metal pool. The main results of physical modeling were tested in the conditions of real ESR on the modernized equipment for melting under the action of longitudinal magnetic fields. It was experimentally established that the longitudinal magnetic field induction of 0.2 Tesla leads to a decrease in the melting current (by up to 20%) and an increase in the amplitude of its oscillations, without direct change in other parameters of the process. If an impulse magnetic field is used, the reduction of the melting current has a cyclic nature, and the value of its reduction depends on the induction and the duration of its impulses and can be up to 70...80%. By means of analysis of the electric modes of the ESR under the influence of an external longitudinal magnetic field induction of 0,2...0,28 Tesla it was established that the frequency of the electrode metal droplet detachment increases by 18...62 %, and the electrode melting rate - by 3...6 %. At the same time, the average diameter of metal droplets decreases by 5...16%, and their mass by 13...41%. It was been experimentally established that the longitudinal magnetic fields at ESR lead to essential refinement of macrostructure of titanium ingots with simultaneous deterioration of the quality of their lateral surface. The optimum values of induction of direct and impulse longitudinal magnetic fields, which ensure the maximum disorientation and macrostructure refinement of ingots of diameter 70...140 mm with minimal deterioration in the quality of their surface and the absence of internal defects. It was found that for the direct magnetic field such induction range is B=0,12...0,22 Tesla, and for the pulse one - B=0,18...0,3 Tesla with the duration of pulses timp=0,9...2,5 s, and pauses - tp = 6...15 s. The temperature dependence of electrical conductivity, viscosity and solidification interval of salt compositions based on CaF2 was investigated. On their basis the salt, threecomponent flux of CaF2 - SrCl2 - Na3AlF6 system for ESR of titanium was developed. Technological recommendations on equipment, materials, regimes for ESR of ingots of titanium alloys in longitudinal magnetic fields were developed. The pilot ingots of titanium alloys VT-6, TS6 and OT-4 were obtained by ESR method in the external magnetic field. It was found that the chemical composition of alloys fully meets the requirements of current standards. The ingot metal is characterized by high chemical and physical homogeneity. The characteristics of the strength of the test samples correspond to the typical values for these alloys, and the characteristics of ductility and impact elasticity exceed on average by 10...25%.

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