Mon'ko O. The electrochemical processes in the systems including mixed ionic-electronic conductor. Кількісні характеристики дисертації

Object of research - the systems with mixed ionic-electronic conductor, the purpose is research of lows of: polarisation and decomposition of polifunctional conductor (PFC); electrorefining of polyvalent metal with PFC on anode; electrochemical intercalation into PFC. Research methods and equipment: theoretical analysis, computer modeling, voltammetry (PI-50.1). Theoretical results and novelty: it was obtained: equations of whole polarisation curve of the system electrode/PFC/electrode; electrorefining process model; model of intercalation electrode charging by constant and linear decreasing current. Practical results and novelty: decomposition effectivity of mixed conducting liquid electrolyte is increased with increasing diffusion layer; it becomes available to calculate parameters of unstable behavior of electrolyser; charging to the definite capacity by linear decreasing current decreases charging time for power source (area of application) in comparison with constant current.