Zarichnyj I. The kinetic of high aliphatic monobasic peroxyacids decomposition in aqueous basic solutions and their reactions with luminol.

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0499U002387

Thesis Registration Form

0499U002387.pdf

Applicant for

Specialization

  • 02.00.04 - Фізична хімія

16-09-1999

Specialized Academic Board

Д 35.051.10

Ivan Franko National University of Lviv

Essay

Hight monoperoxyacids aliphatic row C8-C13. To investigate their stability in basic medium and their oxidative ability and chemiluminescent activity in their reaction with luminol. Chemiluminescent and volumetric method were used. The main ways of decomposition of peroxyacids and main intermediate products of decomposition were ascertained. The kinetic and activative parameters of there reactions are calculated.The critical concentrations of peroxyacids micelloformation in aqueous solutions are determined for the first time.Chemiluminescent method of the determination of monoperoxyacids CCM is proposed. Sphere of apply - organic synthesis, polymerization, analysis.

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