Suprun W. Mechanism and selectivity of homolitic alkenarenes oxidation

The object is process of the radical-chain oxidation of substituted styrenes, reaction of intermediate peroxy radicals, dialkyl peroxide decomposition. The aims to investigate reactivity of aromatic olefines to oxidation. Methodes of research are method of competitive reaction, the gas-liquid chromatography, preparative chromatography, flash chromatography, UV-, NMR-, photoelectrone spectroscopy, masspectrometry, termal analysis, element analysis, quantum method PM3. Kinetics, products of aromatic olefins oxidation, mechanism of peroxy radicals transformation, kinetics and products composition of dialkylperoxide decomposition were investigated. The extended mechanism of alkenarenes oxidation is proposed. Sphere of use are epoxides and peroxides synthesis, the radical chain oxidation of olefines.