Matzui L. Structure and electrophysical properties of the carbon materials and intercalated compounds on their base.

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0506U000033

Applicant for

Specialization

  • 01.04.07 - Фізика твердого тіла

26-12-2005

Specialized Academic Board

Д26.001.23

Essay

.The thesis is devoted to study the regularities of the formation of the acceptor-type intercalated compounds (IGC), composite materials on the base of the carbon materials (CM) of different structural perfection, , as well as to determine the regularities of changing of the mechanisms of transport properties under the formation of graphite structure, its intercalation, modification of the surface and variation of temperature. The possibility of formation IGC with metal chlorides on the base of structurally imperfect CM was proved. As the results of systematic investigation of transport propertie the anomalous behavior of the resistivity, thermo-power within the low temperature range has been detected for thew first time in the IGC The onset of the phase transformation of "quasi-liquid - quasi-crystal" type within the intercalant layers has been detected for the first time as well as the effect of anomalous changing of transport and acoustic characteristics within the range of these phase transformation. Thermodynamic model of IGC existence has been proposed.in frame of which thermodynamic stability have been calculated for a series of IGC and the model of the thermoexfoliated procces have been presented . The main parameters of the synthesis of metal-graphite nanocomposite materials with the predetermined set of structural and physical properties have been determined.

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