Granchak V. Photochemistry of redox transformations of aromatic ketone and peculiarity of their interection with electron donor compounds at presence of acryl monomers.

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0506U000035

Applicant for

Specialization

  • 02.00.04 - Фізична хімія

27-12-2005

Specialized Academic Board

Д26.190.01

Essay

Dissertation is devoted to consideration the nature of excited states of aromatic ketones, and peculiarities of their interaction with electro donor agents. Influence of vinyl monomers on oxigen-restoration reactions of aromatic ketones is studied. Secondary photochemistry reactions, intermediates of photoreduction process and their participation in photopolymerization of acrilates is studied. The subject of intermolecular charge transference, formation of intermediate products and their role in initiation of radical polymerization is considered. Data for physic-chemical bases for creation new materials by photopolymerization for different brunches of industry are presented. Data presented for some materials used in practice. Clearance methods for materials and compounds as well as experimental research methods are described.

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