Ignatyeva T. Features of an electronic spectrum and their influence on physical characteristics of transitional metals and alloys based on these metals

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0508U000132

Applicant for

Specialization

  • 01.04.07 - Фізика твердого тіла

18-02-2008

Specialized Academic Board

Д 64.245.01

Institute of Electrophysics & Radiation Technologies NAS of Ukraine

Essay

Object: electronic-topological transitions under the influence of different external factors. The purpose: an establishment of connection of the changes of physical properties of transition metals and alloys on their basis with features of an electronic spectrum. Methods: a technique of reception of high pressures, measurement of temperature of superconducting transition at 4,2K, a high-sensitivity technique of thermo electromotive measurement, ion channeling. Results: electronic-topological transition - formation of new electronic group in Mo under action of impurity Re is revealed. It is experimentally shown, that the change of topology of a Fermi surface at electronic-topological transition in alloys Mo-Re is accompanied by change of an energy condition of electrons in a narrow energy interval near a bottom of a zone which meets a new cavity of a Fermi surface. By means of a direct method of researches of crystal structures - ion channeling of helium in a crystal, connection of electronic transitions with formation of superstructure in crystal body-centered cubic cell to structure of a solid solution of alloys Mo1-x-Rex is established. Quantitative parameters of electronic-topological transitions in rhenium under influence of impurity of different valences are defined. It is shown that under the changes of topology of a Fermi surface it is necessary to consider not only changes of density of electronic conditions, but also changes of dynamics of electron movement. The field of application: physics of a solid state, the electrophysics, the physics of metals

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