Soloviev S. Design and properties of structured heterogeneous catalysts for the gas-phase redox conversions

Foundations for a new scientific field in the heterogeneous catalysis have been developed - the methods of formation of secondary support and catalytic coating with specified structural characteristics and functional properties on the surface of inert nonporous matrices with various chemical nature and macrostructure. The character of relation between the structurally-sized catalyst characteristics, their surface functional properties (redox, acid-base) and catalytic properties of structured nanophase catalysts has been found, including chemical nature of active components and second support, phase composition, particle size. The influence of modifying additives of s- and p-elements in the composition and structural-size factor on the valence state and location of active sites has been defined for an optimal combination of active components of the catalyst.