Makota O. Catalytic oxidation of olefins С8 by molecular oxygen and hydroperoxides

The general tendency of the influence of nature of metal and ligand, dispergation conditions, nature of carrier and modificator on catalytic activity and selectivity of catalysts and also the influence of nature of substituents on epoxidation ability of hydroperoxide have been established. The kinetic regularities and the mechanism of proceeding of сatalytic oxidation and epoxidation reactions of olefins С8 have been investigated. On the base of the obtained results the general scheme of the oxidation of olefins by molecular oxygen and hydroperoxides in the presence of catalysts adequately described the general regularities reaction proceeding has been proposed. The mathematical model has been developed and the kinetic parameters of these reactions have been determined.