Dutka V. The influence of the reaction medium in the process of converting organic peroxide compounds

The influence of the reaction medium at the reaction of thermal decomposition of aliphatic peroxyacids (РА) was investigated. Found total rate constant and activation energy of the process under study. Primary homoliz O-O group accompanied by reactions induced decomposition, which contribute to the overall process depends on the nature of the reaction medium. . The effect of solvents on oxidative reactions involving PA was studied. Oxidation of pyridine, acridine, quinoline, 8- hydroxyquinoline, pinene, karene, dimethyl sulfoxide occurring on similar mechanisms. A kinetic equation that describes the process of oxidation was proposed. The thermal decomposition of lauryl peroxide, diacyl dyperoxyds in various organic solvents was studied. Found correlation equation linking peroxides decomposition rate constant and the rate of oxidation of various substrates PA with major physical- chemical parameters of solvents. The methods of synthesis of polymer-mineral composites was developed and studied their properties.