Gorbachuk M. Thermodynamic properties of rare-earth silicides and germanides

Українська версія

Thesis for the degree of Doctor of Science (DSc)

State registration number

0516U000883

Applicant for

Specialization

  • 02.00.04 - Фізична хімія

17-11-2016

Specialized Academic Board

Д 26 207 02

Essay

Dissertation is devoted to experimental study of thermodynamic properties of Lanthanoides silicides and germanides of Ln5X3, LnX, LnX2-n composition in wide temperature range, revealing of general regularities of these properties along the series of isostructural compounds end versus noumetal content in compounds. For the first time the of heat capacity and enthalpy of 29 rare earth silicides and germanides, were experimentally determined. The temperatures enthalpies and entropies of phase transitions of these compounds were calculated. Based on above regularities the values of thermodynamic properties of 42 compounds for which these data are absent.

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