Varzats'kyj O. The directed synthesis and physical-chemistry of asymmetrical macrobicyclic tri-diiminates iron (II) complexes

Synthesis strategy of designing iron (II) asymmetrical clathrochelates of the different earlier unknown types was determined, the possibility of elementoxide matrixes application as topochemichal protective group for clathrochelates assembly on the surface and sterical of the metallochelate control by a skeleton of connections formation with vectorially isomeric macrocarcases is shown; macrobicyclic systems immobilized on a surface of inorganic matrixes were received for the first time; 23 new compounds were synthesized. Using structure and molecular analysis and physical-chemistry methods the data on a structure, spectra and properties of the synthesized compounds were researched