Zagrychuk G. Reactions of diazonium tetrafluoroborates with allyl compounds and salts of inorganic and organic acids.

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0400U001137

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

03-04-2000

Specialized Academic Board

Д 35.052.01

Lviv Polytechnic National University

Essay

The interaction of arenediazonim tetrafluoroborates with allyl compounds in presence of thiocyanat-anion, and aromatic diazonium salts with salts of inorganic and organic acids were discovered. Condition of regioselective and regioderective introduction thiocyanat-groups and radical arene in the carbon skeleton of allyl system are discovered, it gave a possibility to synthesize new inaccessible thiocyanates of aralkil range. The region of known Sandmeyer reaction is significally widen by the way of interaction different salts of inorganic and organic acids. It was determined, that in the presence of strong nucleophiles these reactions go off in non-catalytic conditions also. Due to the investigation different organic compounds have antimicrobial and antiwearing properties are synthesized.

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