Kozhura O. Synthesis, structure and properties of binuclear complex rhenium(III) compounds with amino acids

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0400U001905

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

23-06-2000

Specialized Academic Board

Д 08.078.01

Ukrainian State University of Chemical Technology

Essay

Binuclear complexes rhenium (ІІІ) compounds with amino acids. To develop procedures of synthesis, to determine composition, constitution and properties of compounds. Methods are IR- and electron spectroscopy, elemental and thermal analysis, conductometry. Three types complexes rhenium(ІІІ) compounds with amino acids have been obtained. The thermal regrouping of amino acids octachlorodirhenates(III) has been discovered. Trans-cis-isomerization phenomenon of halogenocarboxylates dirhenium(III) has been discovered. The wide spectrum of a biological activity of cis-tetrachlorodi-m-aminocarboxylatodirheniun(III) chlorides has been discovered. The sphere of using is bioinorganic and complexes chemistry, medicine.

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