Bukhtiyarov V. Synthesis and physicochemical properties of homogeneous and mixed-ligand ?-diketonates of manganese (III)

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0400U002714

Thesis Registration Form

0400U002714.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

10-10-2000

Specialized Academic Board

Д 26.190.01

L. V. Pisarzhevskii Institute Of Physical Chemistry of The National Academy of Sciences of Ukraine

Essay

Methods of synthesis Mn(III) trisacetylacetonate, diacetylacetonatecarboxylates and dibenzoylacetonatecarboxylates. These complexes are initiators of the polymerization of vinyl monomers. Occurrence of free radicals during photolysis of Mn (III) acetylacetonate - alcohol system was fixed by UV- and EPR-spectroscopy methods. In the field of 60Co irradiation acetylacetonates of metals demonstrate a sensitizing impact on processes of structuring of the compositions on the basis of copolymer of vinyl chloride and vinyl acetate and protect the derivatives of cellulose from destruction. Application aria is inorganic chemistry.

Read more

Similar theses

0523U100191

Grygorii S. Dmytriv

Interaction of lithium with d-metals and p-elements of III-V groups

0522U100046

Lysenko Andrii B.

Coordination polymers based on 1,2,4-triazole containing ligands

0521U101843

Terebilenko Kateryna Volodymyrivna

Complex oxides based on uni-, bi- and trivalent metals with tetrahedral anions: synthesis, structure and properties

0521U101532

Vadym O. Pavlenko

Polynuclear coordination compounds of transition 3d-metals based on simple and chelating pyrazoles

0521U101380

Seredyuk Maksym L.

Coordination compounds of iron(II) with five- and six-membered N-heterocyclic ligands: structure, spin and phase transitions