Bus'ko N. Block copolymers on the base of vinil monomers and oligomeric initiators (synthesis, structure and properties)

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0401U001872

Thesis Registration Form

0401U001872.pdf

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

30-05-2001

Specialized Academic Board

Д 26.179.01

Institute of Macromolecular Chemistry of NAS of Ukraine

Essay

The methods of synthesis of oligomeric azo- and polyazoinitiators on the base of azo-bis-isobutyrohydrazone of cyclohexanone and butadiene-isoprene rubber have been developed. Threeblock and polyblock copolymers synthesized using oligomeric azoinitiators by the method of photoinitiated radical polymerization were charactherized by differential scanning calorimetry, by small-anglе X-ray and dynamic mechanical analysis. It has been also shown that the photoinitiated radical polymerization method using polyazoinitiators may be applied to obtain block copolymers in the one-stage way to simplify their synthesis

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Files

diss.doc

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