Shevchenko O. Polymerization initiation of vinilic monomers by unsaturated (-diketonates Co (ІІ), Nі (ІІ), Cu (ІІ).

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0401U003444

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

18-12-2001

Specialized Academic Board

Д 26.001.25

Taras Shevchenko National University of Kyiv

Essay

It is shown, that unsaturated acetylacetonates of Co(II) and Ni(II) are highly effective initiators of styrol and methylmetacrylate polymerization. Low energies of polymerization activation are typical for this initiators, it possible to use them at low temperatures. Providing high speed of the process, the y make polymers with high molecular mass and low polydispersive indexes.

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