Тonkopiyeva L. The correlation of annealing polymer process with a chemical structure of macromolecules

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0402U001308

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

23-04-2002

Specialized Academic Board

Д 26.001.25

Taras Shevchenko National University of Kyiv

Essay

Structure reconstruction process of polymers and copolymers under external and internal factors and determination of its mechanism is devoted. It was shown that durable annealing of polymers and copolymers under temperature which is higher than glass transition temperature leads to reconstruction of structure both macromolecules and the system of macromolecules. The mechanism of electrical field effect has been proposed for polymers which are annealing. Electrical forces retard the translation movement of segments and the conformational reconstruction of macromolecules.

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