Berezhnyts'ka O. Synthesis, structure and polymerization of beta-diketonate complexes of 3d- metals (Co, Ni, Cu) with unsaturated alfa - and gama- substitutes

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0402U001601

Thesis Registration Form

0402U001601.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

10-05-2002

Specialized Academic Board

Д 26.218.01

V.I. Vernadskii Institute of General & Inorganic Chemistry NAS of Ukraine

Essay

This dissertation is aimed at the synthesis, study of the structure and polymerization of Co-, Ni- and Cu- complexes with unsaturated diketones. The adducts of copper complexes with dimethylformamide, pyridine and triphenilphosphine have been obtained. The quantum-chemical calculations have been carried out for unsaturated beta-diketones and their complexes. The conditions of polymerization of Co, Ni and Cu complexes with the unsaturated b-diketones have been determined, and the kinetics of their radical polymerization has been studie

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Files

eks1.doc

eks3.doc

exp2.doc

liter.doc

litob1.doc

litob2.doc

p 14.doc

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