Korzh R. Diisopropyl Ether Obtaining over Heterogeneous Catalysts

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0402U001949

Applicant for

Specialization

  • 02.00.13 - Нафтохімія і вуглехімія

07-06-2002

Specialized Academic Board

Д 26.220.01

V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine

Essay

Investigations of the regularities of propene hydration and propan-2-ol extramolecular dehydration for producing diisopropyl ether as antiknock dobes for gasolines over heterogeneous catalysts. Methods of catalytical investigations, gas chromatography, flaming photometry, NMR. It was shown that the water adsorption caused the conversion of classic protonic sites to structural aquacycles with mobile proton. The alcohol extramolecular dehydration including the synchronous migration of electronic density of reactants bonds is proposed. The technology of cation exchange resin shaping was developed. Sphere of use is the petrochemistry.

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