Karpichev E. Reactivity of functional detergents based on a-nucleophiles in processes of acyl group transfer

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0402U002224

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

31-05-2002

Specialized Academic Board

Д 11.216.01

Essay

Objects: a-nucleophiles and functional surfactants based on a-nucleophiles. The aim is search of nucleophilic reagents and systems for cleavage of ecotoxic substrates. Methods: UV-, NMR-spectroscopy, potentiometry. Reactivity of hydroxylamine anion was first established as maximum one among a-nucleophiles known; shown that new functional surfactants are the most powerful nucleophilic systems for the cleavage of phosphorous esters. Field: creation of highly efficient nucleophilic systems.

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