Tkachenko K. Synthesis and Structure of Binuclear Macrobicyclic Tris-azinedioxymate Complexes of Iron (II)

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0402U003069

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

10-10-2002

Specialized Academic Board

Д26.218.01

Essay

The dissertation is devoted to synthesis and structure study of polynuclear clathrochelate tris-azinedioximate iron (II) complexes - new type of the rigid binucleating macrobicyclic systems.The methods of template synthesis of the series of polynuclear fluoroboron-, arylboron-, trifluoromethylgermanium-, trihalogenotin-capped clathrochelate iron (II) complexes with binucleating macrobicyclic homolog tris-azinedioximate ligands were developed. The spectral behaviour of binuclear clathrochelate complexes have been analyzed.

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