Gafijchuk G. Kinetic model of the grafting polymerization initiated from the solid surface

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0403U000517

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

03-02-2003

Specialized Academic Board

Д 35.052.01

Lviv Polytechnic National University

Essay

The thesis is dedicated to the development of the kinetic model of the grafting polymerization initiated from solid surface which takes into account the formation of fixed to the surface radicals, diffusion of the free radicals into volume and additional initiation in volume. This model has been applied to estimate at the quantitative level the kinetic characteristics of the grafting process and to select appropriate experimental conditions for controlled synthesis of polymer brushes.

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