Mitina N. Low-temperature radical initiators on the basis of metal complexes of heterofunctional oligoperoxides

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0403U000838

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

24-02-2003

Specialized Academic Board

Д 35.052.01

Lviv Polytechnic National University

Essay

The method of obtaining oligoperoxidic metal complex initiators is developed in the work. Different factors, which influence features of formation of oligoperoxidic metal complexes (including macro-and microstructure of oligomer ligands) were investigated. Synthesized oligoperoxide metal complexes are able to generate free radicals in water-alkaline medium at 273 K yet. Synthesized oligoperoxide metal complexes serve as the initiators, stabilizers and modifiers of water dispersions of polymers.

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