Trush E. Coordination compounds of 3d- metals with carbacylamidophosphates

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0403U002177

Thesis Registration Form

0403U002177.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

09-06-2003

Specialized Academic Board

Д 26.001.03

Taras Shevchenko National University of Kyiv

Essay

The thesis is focused on the study for 3d?metal ion complexes with a novel ligand system - P,N-substituted structural analogues of b- diketons and the search of main factors influencing composition and structure of the coordination compounds formed by the carbacylamidophosphate ligands. Crystal structure of 15 coordination compounds has been determined and it was proved that in all cases the carbacylamidophosphate species act as anionic ligands. They were coordinated by the metal centers via oxygen atoms of phosphorylic and carbonyl groups forming six-membered chelate cycles. Less commonly, the carbacylamidophosphates could display also tridentate chelate-bridging function via oxygen atoms of CO and PO groups.

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Files

A-ref.doc

Disser.doc

Dodatky-1-X-Ray.doc

Dodatky-1.doc

Forma14.DOC

Titul-aref.doc

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