Raspertova I. Synthesis and study of coordination compounds with aliphatic and aromatic nitrones

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0403U003064

Thesis Registration Form

0403U003064.pdf

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

22-09-2003

Specialized Academic Board

Д 26.001.03

Taras Shevchenko National University of Kyiv

Essay

The dissertation is devoted to study of coordination and chemical properties of aliphatic and aromatic nitrones. The new methods synthesis of the 3d-, 4d-metals and dioxouranium (VI) coordination compounds with nitrones have been elaborated and 26 new complexes have been prepared. The compounds were studied by IR, NMR, ESR and UV-VIS spectoscopies. The crystal structure of the 3 new ligands, 6 new complexes and one diisoxazolidine have been determined by X-Ray single crystal analysis. It was shown that nitrones exist in trans-form. The preliminary investigations of influence nitrone group's coordination in cycloadditon reaction with olefines were undertaken.

Read more

Files

Dodatki.doc

aref--aref.doc

aref--titul-aref.doc

disser.doc

Similar theses

0523U100191

Grygorii S. Dmytriv

Interaction of lithium with d-metals and p-elements of III-V groups

0522U100046

Lysenko Andrii B.

Coordination polymers based on 1,2,4-triazole containing ligands

0521U101843

Terebilenko Kateryna Volodymyrivna

Complex oxides based on uni-, bi- and trivalent metals with tetrahedral anions: synthesis, structure and properties

0521U101532

Vadym O. Pavlenko

Polynuclear coordination compounds of transition 3d-metals based on simple and chelating pyrazoles

0521U101380

Seredyuk Maksym L.

Coordination compounds of iron(II) with five- and six-membered N-heterocyclic ligands: structure, spin and phase transitions