Golichenko O. Synthesis, structure and properties of binuclear cluster rhenium(III) compounds with adamantanecarboxylic acids.

Synthesis and investigation of features of a composition of molecules, chemical, spectral and physicochemical properties derivative of a cluster Re26+ with adamantanecarboxylic acids. Elaboration of the philosophy and specific trajectories of synthesis binuclear halogenocarboxylates of rhenium(III) with adamantanecarboxylic acids and learning of idiosyncrasies of chemical behaviour and constitutions of different structural types adamantanehalogenocarboxylates of dirhenium(ІІІ). Research methods: the element analysis, IR- and electronic spectroscopy, X-ray crystal and thermogravimetric analysis. Halogenocarboxylates of dirhenium(III) with adamantanecarboxylic acids of all possible structural types were synthesized. The complex investigation of methods of synthesis and transmutations of isomeric trans- and cis-tetrahalogenodi-m-carboxylates of dirhenium(III) was conducted. Some kinetic regularities of a trans-cis isomerization for halogenocarboxylates of dirhenium(III) in electron donor solvents were learnt, and guesses of its mechanism was made. It's exhibited availability of further examination of different views of bioactivity of this class complexes, including as antitumoral drugs with a hypotoxicity. Sphere of use: coordination and bioinorganic chemistry, medicine.