Baranovskyj V. Reactions of aromatic diazonium salts with biunsaturated compounds with isolated double bonds in presence of thiocyanat-nucleophile

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0404U001577

Applicant for

Specialization

  • 02.00.03 - Органічна хімія

29-03-2004

Specialized Academic Board

Д 35.052.01

Lviv Polytechnic National University

Essay

The interaction of arenediazonium salts with biunsaturated compounds with isolated acrylic and allyl fragments in presence of thiocyanates was studied. The conditions for synthesis of mono- and biadducts of thiocyanatoarylation of glycols diacrylates and N,N-methylenbisacrylamide were designed. Is established, that thiocyanatoarylation of diallyl systems limits by monoadducts formation, irrespective of conditions of reaction. A number of new compounds are synthesized, separate from which one own antimicrobial properties.

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