Evtukh A. Interaction of graphite-intercalated lithium fluoride with electron-seeking reagents.

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0404U001965

Applicant for

Specialization

  • 02.00.01 - Неорганічна хімія

02-04-2004

Specialized Academic Board

Д 08.078.01

Ukrainian State University of Chemical Technology

Essay

Object researches - processes of interactiographite-intercalated lithium fluoride with electron-seeking reagents. The purpose of work - determination of the basic laws of interaction of graphite-intercalated lithium fluoride with electron-seeking reagents. With use the NMR-spectroscopy on nucleuses 7Li and 19F, chemical and component analysis, X-radiography and quantum-chemical accounts (MPDP, ab initio) is established composition and structure of fluorinated graphite after a stage electrochemical intercalation of ions Li+ and is established laws of interaction intercalated LiF with electron-seeking reagents in aqueous and non-aqueous solutions. . The results of researches have allowed to develop technology of salvaging of the fulfilled lithium batteries with (CFx)n-cathode. The product of processing - lithium tetrafluoroborate is tested in lithium elements. A range of application - chemistry of fluorides, environment.

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