Ishkov B. Reversible affixation of molecular oxygen in mixed ligant histydinatdiamine complexes cobalt(II)

The object is complexformation and inversed joined moleculas oxygen in mixed ligand systems, including reaction of formation not only in mixed legand complexes. The aims the thesis is devoted to the research of new oxygenfixing systems, studying the process of complex formation and inversed joined moleculas oxygen in mixed ligand systems, including reaction of formation not only in mixed legand complexes, but in homoheneous complexes with diamine and histydinum. With the help of pH-measuring, manometric, mole relations, simultaneous registration of pH-solution and amount of joined oxygen it is established the composition of formed complexes and their participation in acidic basic eguilibrium depending on pH-solution; it is also established the processes going in mixed ligand and homogeneous systems. The new it is developed an original approach to establishing of mechanism and numerous characteristics of complex formation process and oxygination in complex systemes in which the formation of more than 30 complexes take part.