Kupriyan D. Synthesis and properties of 2,6- and 2,6,7-1H-benzo[de]isoquinoline-1,3(2H)-dione substituted

Research Object: photoluminophores naphthalimide derivatives: methods of synthesis, spectral properties. Research Aim: the development of convenient methods of synthesis 4- and 4,5-substituted naphthalic acid N-alkylimides and research of physico-chemical properties of new luminescent structures from naphthalimide series. Methods and devices: organic synthesis, UV, IR and NMR spectroscopy, mass-spectrometry. Theoretical results and the novelty: new methods of synthesis for lu-minophores of naphthalimide series based on the reactions of primary amines acylation by naphthalic anhydrides and naphthalimides phase transfer catalytic alkylation by al-kylbromides have been proposed. The reactivity of some imides and anhydrides of naphthalic acid derivatives in reaction of aminolysis by alkylamines have been estimated on the basis of kinetic data. Practical results and their's significance: the series of homo- and hetercore luminophores bis-naphthalimides derivatives have been synthesized. Physical and spectral properties of the pre-pared compounds have been investigated. The possible fields of its application as luminophores, has been revealed. Inculcation degree: publications, reports on scientific conferences, usage in research work and pedagogical practice at Research Units and high schools of Ukraine. Effectiveness: is ensured with use of more perfect techniques of synthesis of photoluminophores naphthalimide derivatives. Spere of Usage: chemistry, electronics.