Batog O. Single-stage synthesis of poly(epoxy acrylate)s by photochemically induced polymerization.

Українська версія

Thesis for the degree of Candidate of Sciences (CSc)

State registration number

0404U004981

Applicant for

Specialization

  • 02.00.06 - Хімія високомолекулярних сполук

01-12-2004

Specialized Academic Board

Д 26.179.01

Institute of Macromolecular Chemistry of NAS of Ukraine

Essay

The single-stage synthesis of poly(epoxy acrylate)s by photochemically induced polymerization, the systems, epoxies/acrylate , was induced by tri(phenyl)-sulfonium exafluorophosphate. Kinetics of the photochemically induced reaction was studied. After switching-off the UV-irradiation of a mixture, the "dark" polymerization effect was observed. The structure and properties of the obtained polymers proved to depend on irradiation regime and inhibitors content. Physico-mechanical properties were shown to be controlled by their structure.

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